Second Natural Occurrence of KFeS2 (Hanswikeite): An Inclusion in Diamond from the Udachnaya Kimberlite Pipe (Siberian Craton, Yakutia)

نویسندگان

چکیده

Potassium sulfide KFeS2 (hanswilkeite) has been identified in polymineralic inclusions a diamond from the Udachnaya kimberlite pipe (Siberian craton, Yakutia). This is second occurrence of hanswilkeite nature and first one mantle-derived samples. Sulfide monoclinic, space group—C 2/c. Its crystal structure consists chains with K interstices. The tetrahedra are centered by iron ions linked edges, thus forming [FeS2] frameworks. strongest lines electron diffraction powder pattern 7.05 Å—(200); 5.34 Å (02¯0); 3.05 (22¯0), angles between directions <22¯0/02¯0>—60° <22¯0/200>—30°. found as discrete phase within consisting apatite, ilmenite, chondrodite, phlogopite, dolomite, fluid phase. data obtained composition (KFeS2) inclusion other rare minerals (chondrodite, Mg-apatite, Cr-ilmenite) primary testify to important role metasomatic processes formation.

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ژورنال

عنوان ژورنال: Minerals

سال: 2023

ISSN: ['2075-163X']

DOI: https://doi.org/10.3390/min13070874